Long-term sun exposure and damage from the sun's ultraviolet light leads to photoageing, which causes most wrinkles and undesirable skin changes, including skin cancer.
Of course, staying out of the sun and wearing UV-protective clothing are the best ways to prevent wrinkles, but most of us are unlikely to really do that. So, using a broad-spectrum sunscreen (offering UVA and UVB protection with an SPF of at least 15, the NHS recommends) every day is the most effective and realistic way to protect skin and look younger.